In simple terms, harmonics are extra frequencies that when present in an electrical circuit, distort the AC sine wave. A harmonic of a wave is a component frequency of the signal that is an integer multiple of the fundamental frequency. For example, if the fundamental frequency is f, the harmonics have frequencies 2f, 3f, 4f... etc.
Harmonic frequencies are equally spaced by the width of the fundamental frequency and can be found by repeatedly adding that frequency. In the case of the Australian electricity supply, the fundamental frequency is 50Hz. The frequencies of the harmonics are 100Hz, 150Hz, 200Hz, 250Hz, 300Hz, 350Hz and so on.